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Energy Sequence of the Lowest Antibonding Orbitals in Symmetrical Didehydro[n]annulenes with n = 4N+2

✍ Scribed by Fabian Gerson; Joanna Jachimowicz; Masazumi Nakagawa; Masahiko Iyoda


Publisher
John Wiley and Sons
Year
1974
Tongue
German
Weight
423 KB
Volume
57
Category
Article
ISSN
0018-019X

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Perimeter-Type Structures in Charged [4n
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The tetra(terf-butyl)[l4]annuleno[l4]annulene 1 is transformed, oia alkali metal reduction, into its radical monoanion, dianion, radical trianion, and tetraanion. The paramagnetic species are characterized by ESR and ENDOR spectroscopy and the diamagnetic species by 'Hand I3C-NMR spectroscopy. Well-