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Energy localization and photochemical reactivity. The photochemical of ethyl 4-(1-naphthyl)-4,4-dimethylbutenoate.

✍ Scribed by Stephen S. Hixson; Joseph C. Tausta


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
198 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis


In our study of excited state migration reactions' we have turned to au examination of the influence of excitation energy localization on the course of reaction of bichromophoric systems.

In a series of compounds X-(CR2)n-Y in which X ie an aromatic ring, Y is a substituted vinyl group, and (CR2)n is a saturated carbon insulator, we are interested in learing how the photo-


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In contrast to recent claims by Rhodes and Glidewell, comparison of both ESR and electronic absorption spectra shows that the photoproduct of the recently characterized radical cation of bicyclo[ 3.3.0]octa-2,6-diene-4,8-diyl is identical to the 1,4dihydropentalene radical cation, i.e. a linear conj