The classical and quantum-mechanical fre
β
K. Singer; W. Smith
π
Article
π
1987
π
Elsevier Science
π
English
β 371 KB
The classical and quantum-mechanical free energies of crystalline (fee) argon were determined at two state points by classical and path integral Monte Carlo methods. The quantum corrections to the free energy, energy and pressure so obtained are compared with corrections based on the harmonic approx