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Energy gradient in a multi-configurational SCF formalism and its application to geometry optimization of trimethylene diradicals

✍ Scribed by Shigeki Kato; Keiji Morokuma


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
493 KB
Volume
65
Category
Article
ISSN
0009-2614

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✦ Synopsis


Prc\iour methods of analytic eahtation oC ths potential cncg? pltxiient with tcspcct to nuclear axwdinxcs hate been limited to sinslc dctcrminant llxtte-I-o& xtrcfunctions. An c\pr&on and a practical mcthnd arc prcslrntcd fnr anaiylic gralimr crdu;ltion for MCSCI' t\avcfunctionr of twtain witlcly applktblc t)pcs A gwtnctry optintilation of tri: mcthylcnc diradial rhction interntediatcs has been xtu~ll~ accontplirhrd by the use 01' the snrrgk' pdicnt for an ab tmtio MC SCI' w3vcfunction.