𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Energy dependence of H-exchange versus CC bond formation in the complex [CH3OH CH2CH+2]: unimolecular and bimolecular studies

✍ Scribed by David J. McAdoo; Mohammed S. Ahmed; Charles E. Hudson; C.S. Giam

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
911 KB
Volume
100
Category
Article
ISSN
0168-1176

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

A photoionization study of the ion-neutr
A photoionization study of the ion-neutral complexes CH3CH+CH3·CH2CH3] and CH3CH2CH+CH3·CH3in the gas phase: Formation, H-transfer and C—C bond formation between partners, and channeling of energy into dissociation
✍ John C. Traeger; Charles E. Hudson; David J. McAdoo 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 910 KB

## Photoionization mass spectrometry was used to investigate the dynamics of ion-neutral complex-mediated dissociations of the Iz-pentane ion (1). Reinterpretation of previous data demonstrates that a fraction of ions 1 isomerizes to the 2-methylbutane ion (2) through the complex [CHaCH+CHa'CH,CH,

Evidence for complex formation in the re
Evidence for complex formation in the reactions of CH+3 and CD+3 with CH3OH, CD3OD, and C2H5OH
✍ Richard D. Smith; Jean H. Futrell 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 447 KB

Product distributions for the reactions of CH$ and CDf with methanol, methanol-da, and ethanol studied in a tandemkm CpdOtrOTl resonance mass SpeCtrOmeter are reported. The major reaction pathways may 5c rationalized in terms of 3x1 intermediate species havving a pro&mated ether structure. The react

Theoretical study of the CH bond dissoc
Theoretical study of the CH bond dissociation energies of CH4, C2H2, C2H4, and H2C2O
✍ Charles W. Bauschlicher Jr.; Stephen R. Langhoff 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 554 KB

The successive C-H bond dissociation energies of CH,, &Hz. C2H4, and H&O (ketene) are determined using large basis sets and a high level of correlation treatment. For CHI, C2H2, and C2H4 the computed values are in excellent agreement with experiment. Using our results we recommend 107.9 +2.0 and 96.