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Energy and entropy of formation of crystalline 1-pentadecanoic acid from the ideal gaseous monolayer at the air/water interface

โœ Scribed by Pallas, N. R.; Pethica, B. A.


Book ID
118244697
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
342 KB
Volume
8
Category
Article
ISSN
0743-7463

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Monolayer Formation of Alkyl Chain-Conta
โœ Weijiang He; Chaoyang Jiang; Fang Liu; Zihou Tai; Yingqiu Liang; Zijian Guo; Lon ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 127 KB

In the four studied monoalkyl phosphoric acids (n-C(12)H(25)OPO(OH)(2), MDP; n-C(14)H(29)OPO(OH)(2), MTP; n-C(16)H(33)OPO(OH)(2), MHP; and n-C(18)H(37)OPO(OH)(2)MOP), only MOP can form an insoluble monolayer at the air/water interface (pH 5.6), suggesting that the longer alkyl chain (> or =C(18)) is