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Energy accumulation by migration to geometric trap configurations of randomly distributed molecules

✍ Scribed by J. Manz


Book ID
103016317
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
344 KB
Volume
72
Category
Article
ISSN
0009-2614

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✦ Synopsis


Energy accumulation by migration to moving acceptors is considerably enhanced when the excitation is trapped in favourable geometric configurations of randomly dlstnbuted matnx-isolated molecules. The geometric traps are identified as pairs of molecules with a short intermolecular &stance. The correspondmg macroscopic rate coefficients are related to the microscopic energy-transfer rate coefficients. using a simple extcnslon of the model of Blumen et aI.