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Energetics, stabilities, and possible structures of CH5+(CH4)n clusters from gas phase study of equilibriums CH5+(CH4)n-1 + CH4 = CH5+(CH4)n for n = 1-5

โœ Scribed by Hiraoka, Kenzo; Kebarle, Paul

Book ID
127152776
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
590 KB
Volume
97
Category
Article
ISSN
0002-7863

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Gas-phase stability and structure of clu
Gas-phase stability and structure of cluster ions CH5+(CH4)n with n=1-9
โœ Kenzo Hiraoka; Toshiharu Mori ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 422 KB

Thermochemical data, AH:\_ I." and ASi\_ ],", for the clustering reactions CH: (CH,),\_, +CH,=CH: (CH,),, with n= 1-9 were measured using a pulsed electron-beam mass spectrometer. Both -AH:-,,n and -AS:\_, ,n show irregular decreases between n = 2 and 3, and 7 and 8, the latter indicating the forma