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Energetics of organic solid-state reactions: the topochemical principle and the mechanism of the oligomerization of the 2,5-distyrylpyrazine molecular crystal

โœ Scribed by Peachey, N. M.; Eckhardt, C. J.


Book ID
126187094
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
944 KB
Volume
115
Category
Article
ISSN
0002-7863

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Electronic structure and photochemistry
โœ N.M. Peachey; C.J. Eckhardt ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 357 KB

The single crystal spectra of2,5-distyrylpyrazine (DSP) were obtained in the frequency region of demonstrated photochemical activity. Two observed transitions, n-E\* and ~-~\*, are assigned at 23300 and 25400 cm ~, respectively. The lower energy transition is shown to be responsible for the reported