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Energetics of high surface area silicas

✍ Scribed by P.D Maniar; A Navrotsky


Book ID
115987287
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
452 KB
Volume
120
Category
Article
ISSN
0022-3093

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Structural studies of high surface area
✍ L.F. Gladden; M. Vignaux; P. Chiaranussati; R.W. Griffiths; S.D. Jackson; J.R. J πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 888 KB
High-silica zeolites: a relationship bet
✍ Eric C. Moloy; Lilian P. Davila; James F. Shackelford; Alexandra Navrotsky πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 English βš– 502 KB

High-silica zeolites are 5.6-15.5 kJ/mol less stable in enthalpy than a-quartz--the stable polymorph of silica under ambient conditions. Previous studies have correlated these energetic metastabilities to molar volumes and framework densities. In this study, we consider the question of whether these