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Energetics of bond association and dissociation reactions of metallo-carbene porphyrins: Models for cytochrome P-450

✍ Scribed by T.K. Jones Jr.; MaureenJ. Kendrick


Book ID
107901163
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
76 KB
Volume
36
Category
Article
ISSN
0162-0134

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## Abstract Kinetic and mechanistic studies on the formation of an oxoiron(IV) porphyrin cation radical bearing a thiolate group as proximal ligand are reported. The **SR** complex, a functional enzyme mimic of P450, was oxidized in peroxo‐shunt reactions under different experimental conditions wit