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Energetics of adsorption of neutral and charged molecules at the air/water interface by second harmonic generation: Hydrophobic and solvation effects

✍ Scribed by Castro, Alonso; Bhattacharyya, Kankan; Eisenthal, Kenneth B.


Book ID
120555618
Publisher
American Institute of Physics
Year
1991
Tongue
English
Weight
679 KB
Volume
95
Category
Article
ISSN
0021-9606

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We present an experimental study of the adsorption of hydrophobic highly charged polyelectrolytes on a neutral and hydrophobic surface, the air/water interface. The polymer was a randomly sulphonated polystyrene with charge fractions between 0.3 and 0.9 and the adsorbed layers were characterised by