✦ LIBER ✦

Energetic Salts of the Binary 5-Cyanotetrazolate Anion ([C2N5]−) with Nitrogen-Rich Cations

✍ Scribed by Dr. Margaret-Jane Crawford; Prof. Dr. Thomas M. Klapötke; Franz A. Martin; Dr. Carles Miró Sabaté; Magdalena Rusan

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 559 KB
Volume: 17
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.201002161

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Nitrogen-Rich Salts Based on the Energet

Nitrogen-Rich Salts Based on the Energetic 5,5′-(Hydrazine-1,2-diyl)bis[1H-tetrazolide] Anion

✍ Moritz Eberspächer; Thomas M. Klapötke; Carles Miró Sabaté 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 German ⚖ 473 KB

## Abstract magnified image The reaction of 5,5′‐(hydrazine‐1,2‐diyl)bis[1__H__‐tetrazole] (HBT) with N‐bases yielded a new family of energetic N‐rich salts based on the 5,5′‐(hydrazine‐1,2‐diyl)bis[1__H__‐tetrazol‐1‐ide] anion with ammonium (see **1**), hydrazinium (see **2**), guanidinium (see *

Energetic Nitrogen Rich Salts of N,N-bis

Energetic Nitrogen Rich Salts of N,N-bis[1(2)H-Tetrazol-5-yl]amine

✍ Y. Guo; H. Gao; B. Twamley; J. M. Shreeve 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 191 KB 👁 2 views

Modern high-energy density materials (HEDM), where energetic nitrogen rich salts are among the most recent and exciting developments, continue to attract considerable interest. [4] The use of nitrogen-containing anions and cations contributes to high heats of formation and high densities arising fro

Tris(dimethylamino)sulfoniumcyclopentadi

Tris(dimethylamino)sulfoniumcyclopentadienide [TAS]+[C5H5]− and Tris(dimethylamino)-sulfoniumpyrrolide [TAS]+[C4H4N]−: Two Isostructural Salts with “Naked” Anions A− and the “Inverse” Sandwich-Cations [{(Me2N)3S}2A]+ (A = C5H, C4H4N−)

✍ Jens Wessel; Prof. Dr. Ulrich Behrens; Enno Lork; Prof. Dr. Rüdiger Mews 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 618 KB

Diamagnetic π-Dimers of the [1,2,5]Thiad

Diamagnetic π-Dimers of the [1,2,5]Thiadiazolo[3,4-c][1,2,5]thiadiazolidyl Radical Anion in the Crystalline State: Preparation and X-ray Crystal Structure of a [(Me2N)2CC(NMe2)2]2+[(C2N4S2)2]2– Salt

✍ Nina P. Gritsan; Anton V. Lonchakov; Enno Lork; Ruediger Mews; Elena A. Pritchin 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB

Asymmetric salt effects on anion/cation

Asymmetric salt effects on anion/cation reactions: A comparative study of the [Fe(CN)6]4− + [Co(NH3)5pz]3+ and [Ru(NH3)5pz]2+ + [Co(C2O4)3]3− reactions

✍ F. Muriel; R. de la Vega; F. Sánchez; R. Jiménez; R. Prado-Gotor; F. Pérez; P. P 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 131 KB 👁 2 views

## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4−^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3−^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__

Cationic Brønsted Acids for the Preparat

Cationic Brønsted Acids for the Preparation of SnIV Salts: Synthesis and Characterisation of [Ph3Sn(OEt2)][H2N{B(C6F5)3}2],[Sn(NMe2)3(HNMe2)2][B(C6F5)4] and [Me3Sn(HNMe2)2][B(C6F5)4]

✍ Yann Sarazin; Simon J. Coles; David L. Hughes; Michael B. Hursthouse; Manfred Bo 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 227 KB 👁 1 views

## Abstract Ph~3~SnN(SiMe~3~)~2~ (1) was prepared in good yields by reaction of [{NaN(SiMe~3~)~2~}~2~·THF] (2) with Ph~3~SnF. Treatment of 1 with [H(OEt~2~)~2~][H~2~N{B(C~6~F~5~)~3~}~2~] (4) in dichloromethane afforded the stannylium cation [Ph~3~Sn(OEt~2~)][H~2~N{B(C~6~F~5~)~3~}~2~] (5), which was