ENDOR, triple resonance and ESR studies of spin-trapped radicals in autoxidized linoleic acid and its deuterated derivatives
โ Scribed by Jeffrey C. Evans; Simon K. Jackson; Christopher C. Rowlands; Martin D. Barratt
- Book ID
- 115739214
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 377 KB
- Volume
- 835
- Category
- Article
- ISSN
- 0005-2760
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Radicals generated in linoleic acid and deuterated linoleic acid have been trapped by the spin trap 2-methyl-2-nitroso-propane & q % i = z = 7 GOOH +N-b (MNP) and identified by electron spin resonance (ESR) and ENDOR spectroscopy. The formation of two distinct secondary alkyl radical adducts (o
Multiple resonance spcclra were oblained from lhe radical anion or perfluoro4.4'-bipyridyl in lelrahqdrofuran witi polassium as counlerion Fluorine absorptions were observed in lhe ENDOR speclrum with hyperfine wupling ~nslanl~ of 0.596 and 0.105 mT\_ A general TRIPLE experiment showed lhem lo be op
## Abstract The relative signs and absolute values of the hyperfine coupling constants of different methoxyโ1,4โbenzoquinones were measured by ESR, ENDOR and TRIPLE resonance spectroscopy. Reactions of 1,4โbenzoquinone and 1,4โhydroquinone with methanol took place in alkaline methanol, giving rise