ENDOR and ESEEM investigation of the Ni-containing superoxide dismutase
โ Scribed by Hong-In Lee; Jin-Won Lee; Tran-Chin Yang; Sa-Ouk Kang; Brian M. Hoffman
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 373 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1432-1327
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Larvae of the black swallowtail butterfly, Papilio polyxenes, the southern armyworm, Spodoptera eridania, and the cabbage looper, fiichoplusia ni, have different feeding habits and dietary breadth, which contributes to differences in their exposure and tolerance to dietary prooxidant allelochemicals
## Abstract In the present DFT study, the catalytic mechanism of H~2~O~2~ formation in the oxidative halfโreaction of NiSOD, EโNi(II) + O + 2H^+^ โ EโNi(III) + H~2~O~2~, has been investigated. The main objective of this study is to investigate the source of two protons required in this halfโreactio