Endohedral Metal Complexes of Cyclophanes
โ Scribed by Rolf Gleiter; Bernhard J. Rausch; Rolf J. Schaller
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
Three conditions must be met if an endohedral metalโfullerene complex is to be stable : 1. Metal valence orbitals and fullerene frontier orbitals must have complementary symmetry. 2. The metal atomic orbitals must fit inside the fullerene cavity. 3. The resulting complex must have a closedโshell con
In the following study, a mechanism is postulated whereby [C&M]"+ endohedral complexes may show an exceptionally large vibrational contribution to the dipole polarisability. Ab initio calculations are carried out for the complexes [C&i] +, [ Caa] + and [C&$#+\_ A simple classical analysis of the res