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Endohedral Metal Complexes of Cyclophanes

โœ Scribed by Rolf Gleiter; Bernhard J. Rausch; Rolf J. Schaller


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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In the following study, a mechanism is postulated whereby [C&M]"+ endohedral complexes may show an exceptionally large vibrational contribution to the dipole polarisability. Ab initio calculations are carried out for the complexes [C&i] +, [ Caa] + and [C&$#+\_ A simple classical analysis of the res