## Abstract 1,2 __exo__‐Diiodo‐norbornane (**4**) was prepared from norcamphor hydrazone by oxidative iodination and subsequent rearrangement of the 2,2‐diiodo‐bicyclo [2.2.1]heptane (**2**). The stable α‐iodohydrazone **11** was obtained from 1‐iodo‐bicyclo[2.2.1]heptan‐2‐one (**10**), which itsel
endo,endo- and exo,exo-Bicyclo[1.1.0]butane-2,4-dimethanol Dimesylate: Synthesis, Structure and Solvolysis
✍ Scribed by T. William Bentley; Gareth Llewellyn; Thomas Kottke; Dietmar Stalke; Carsten Cohrs; Edith Herberth; Ulrike Kunz; Manfred Christl
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 495 KB
- Volume
- 2001
- Category
- Article
- ISSN
- 1434-193X
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## Abstract A number of stereoisomeric N‐[aryl(alkyl, cycloalkyl)carbonyl]‐exo(endo)‐5‐aminomethylbicyclo[2.2.1]hept‐2‐enes have been synthesized from bicyclo[2.2.1]hept‐2‐en‐exo(endo)‐5‐carbonitrile via reduction of the latter by lithium aluminum hydride and subsequent reactions of the resulting a
## Abstract The title compound **1** is a further example of an olefinic alcohol that undergoes ether formation under basic conditions **(→ 3)** although the double bond is not activated by an electron‐attracting group. This unusual reactivity is due to steric compression, which is increased in the