Inhaltsu È bersicht. 1,1,3,3,5,5-Hexakis(dimethylamino)-1k 5 -3k 5 -5k 5 -[1,3,5]triphosphinin (5) reagiert mit (Benzonitril) 2 PdCl 2 zu dem Chelat-Komplex Dichloro(dodeca-N-methyl-1k 5 ,3k 5 ,5k 5 -1,3,5-triphosphinin-1,1,3,3,5,5-hexaamin-C 2 ,C 4 )palladium ( ). Wird 6 in Pyridin-d 5 gelo È st, s
Encyclopedia of Reagents for Organic Synthesis || 1,1,1,3,3,3-Hexakis(dimethylamino)-1λ 5 , 3λ 5 -diphosphazenium Fluoride
✍ Scribed by Schwesinger, Reinhard
- Book ID
- 121796695
- Publisher
- John Wiley & Sons, Ltd
- Year
- 2001
- Tongue
- English
- Weight
- 57 KB
- Category
- Article
- ISBN-13
- 9780470842898
No coin nor oath required. For personal study only.
✦ Synopsis
Contains A Database Of Approximately 70,000 Reactions And 4000 Of The Most Frequently Consulted Reagents. Fully Searchable By Structure And Sub-structure, Reagent, Reaction Type, Experimental Conditions, And Keyword. Also Includes A Searchable Interface: Acronym Finder (an Interface For Scientific And Technical Acronyms, Symbols, And Abbreviations).
📜 SIMILAR VOLUMES
Professor Heinrich No È th zum 70. Geburtstag gewidmet Inhaltsu È bersicht. Die Darstellung von 1,1,3,3,5,5-Hexakis(dimethylamino)-k 5 -[1,3,5]triphosphinin (4) und der Bildungsweg aus Methyl-bis(dimethylamino)difluorophosphoran (1) und n-Butyllithium werden beschrieben. Das che-mische Verhalten der
I ,I ,3,3 -Tetrakis(dimethylamin0) -1 h5,3h5diphosphete, 1, reacts with cyanoformic acid methyl ester to form two isomers of the title compound 2. Properties, NMR, mass, and IR spectra of 2, as well as the molecular and crystal structure of the E isomer of 2, are described and discussed.
1, I , 3,3-Tetrakis (dimethylamino)-I k5,3k5-diphosphete, 1, reacts with diphenylchlorophosphane to yield I , I , 33tetrakis (dimethylamino)-4-diphenylphos-phany1-I,2-dihydro-3k5-[1,3]diphosphetium chloride, 2, or, depending on the reaction conditions, the isomer compound 3. The cation of 2 is depro