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Encyclopedia of Reagents for Organic Synthesis || 1,1,1,3,3,3-Hexakis(dimethylamino)-1λ 5 , 3λ 5 -diphosphazenium Fluoride

✍ Scribed by Schwesinger, Reinhard


Book ID
121796695
Publisher
John Wiley & Sons, Ltd
Year
2001
Tongue
English
Weight
57 KB
Category
Article
ISBN-13
9780470842898

No coin nor oath required. For personal study only.

✦ Synopsis


Contains A Database Of Approximately 70,000 Reactions And 4000 Of The Most Frequently Consulted Reagents. Fully Searchable By Structure And Sub-structure, Reagent, Reaction Type, Experimental Conditions, And Keyword. Also Includes A Searchable Interface: Acronym Finder (an Interface For Scientific And Technical Acronyms, Symbols, And Abbreviations).


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Inhaltsu È bersicht. 1,1,3,3,5,5-Hexakis(dimethylamino)-1k 5 -3k 5 -5k 5 -[1,3,5]triphosphinin (5) reagiert mit (Benzonitril) 2 PdCl 2 zu dem Chelat-Komplex Dichloro(dodeca-N-methyl-1k 5 ,3k 5 ,5k 5 -1,3,5-triphosphinin-1,1,3,3,5,5-hexaamin-C 2 ,C 4 )palladium ( ). Wird 6 in Pyridin-d 5 gelo È st, s

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Professor Heinrich No È th zum 70. Geburtstag gewidmet Inhaltsu È bersicht. Die Darstellung von 1,1,3,3,5,5-Hexakis(dimethylamino)-k 5 -[1,3,5]triphosphinin (4) und der Bildungsweg aus Methyl-bis(dimethylamino)difluorophosphoran (1) und n-Butyllithium werden beschrieben. Das che-mische Verhalten der

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1, I , 3,3-Tetrakis (dimethylamino)-I k5,3k5-diphosphete, 1, reacts with diphenylchlorophosphane to yield I , I , 33tetrakis (dimethylamino)-4-diphenylphos-phany1-I,2-dihydro-3k5-[1,3]diphosphetium chloride, 2, or, depending on the reaction conditions, the isomer compound 3. The cation of 2 is depro