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Encapsulated AlCl3: a convenient catalyst for the alkylation of benzene with dodecene

✍ Scribed by Kusoomjin Srirattnai; Somsak Damronglerd; Shinzo Omi; Sophon Roengsumran; Amorn Petsom; Guang-Hui Ma

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
184 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

A novel method for the encapsulation of AlCl 3 was successfully carried out using an insoluble polymer wall. The polymer wall was formed by the reaction of poly(styrene-co-dimethylaminoethyl methacrylate) and hydrogenated telechelic polybutadiene containing -COOH groups. The encapsulated AlCl 3 was used to catalyze the Friedel-Crafts alkylation of benzene with dodecene. The alkylbenzenes were obtained in excellent yields and the encapsulated AlCl 3 catalyst was separated by simple filtration.

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