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Enantiospecific synthesis of (R)-1,7-dioxaspiro [5.5]undecane [major component of olive fruit fly (Dacus Oleae) sex pheromone] from d-Fructose

✍ Scribed by Isidoro Izquierdo Cubero; Maria T. Plaza López-Espinosa; Rafael Acuña Castillo


Publisher
Springer
Year
1991
Tongue
English
Weight
581 KB
Volume
17
Category
Article
ISSN
0098-0331

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Synthesis of Enantiomerically Pure 1,7-D
✍ Priv.-Doz. Dr Hartmut Redlich; Priv.-Doz. Dr Wittko Francke 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 262 KB 👁 1 views

On reduction with NaBH4 in methanol (or 2-propanol) or LiAlH4 in tetrahydrofuran (THF), the 2-acylindoles 1 are converted into the 2-( 1-hydroxyalky1)indole derivatives 2. The 2-(3-dimethylaminopropionyl)indoles l c and Id are obtained from the 2-acetylindoles laL3] and lbI4], respectively, by Manni