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Enantiospecific Formal Total Syntheses of (−)-Salicylihalamides A and B from d -Glucose and l -Rhamnose

✍ Scribed by Yang, KyoungLang; Haack, Torsten; Blackman, Burchelle; Diederich, Wibke E.; Roy, Subho; Pusuluri, Srinivas; Georg, Gunda I.


Book ID
126167387
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
59 KB
Volume
5
Category
Article
ISSN
1523-7060

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Short, Enantiospecific Syntheses of Indo
✍ Charles W. Jefford; Krzysztof Sienkiewicz; Steven R. Thornton 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 German ⚖ 906 KB

## Abstract The 1__H__‐pyrrole derivative obtained from diethyl L‐glutamate hydrochloride and tetrahydro‐2,5‐dimethoxyfuran was cyclized with BBr~3~ to ethyl (5__S__)‐5,6,7,8‐tetrahydro‐8‐oxoindolizine‐5‐carboxylate (18). Catalytic hydrogenation of 18 over Pd/C in AcOH gave ethyl (5__S__,8a__R__)‐o