✦ LIBER ✦
Enantiospecific first total synthesis of (+)-cis,anti,cis-3-hydroxy-1,8,12,12-tetramethyl-4-oxatricyclo[6.4.0.02,6]dodecan-9-yl senecioate, the optical antipode of a natural thapsane isolated from Thapsia villosa
✍ Scribed by A. Srikrishna; K. Anebouselvy
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 271 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The enantiospecific first total synthesis of 10-hydroxy-10,11-epoxythapsan-5-yl senecioate (+)-1f, the enantiomer of the natural thapsane isolated from Thapsia villosa var minor, has been accomplished starting from (R)-carvone.