Enantiospecific synthesis of [7R,6S,5S,4
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G.S.C. Srikanth; Urlam MuraliKrishna; Girish K. Trivedi
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Article
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2002
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Elsevier Science
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French
β 75 KB
A short and efficient synthesis of [7R,6S,5S,4R]-triacetoxy-(-)-goniotriol starting form D-glucose is described. A sequence of ring closing metathesis (RCM) followed by a PCC oxidation was used to construct the core six-membered a,b-unsaturated lactone moiety.