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Enantiospecific Desorption of R - and S -Propylene Oxide from a Chiral Cu(643) Surface

✍ Scribed by Horvath, Joshua D.; Gellman, Andrew J.


Book ID
126003842
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
39 KB
Volume
123
Category
Article
ISSN
0002-7863

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A Short Synthesis of (R,R)-(-)-Pyrenopho
✍ Mali, Raghao S. ;Pohmakotr, Manat ;Weidmann, Beat ;Seebach, Dieter πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 751 KB

## Abstract Analysis of the known syntheses of pyrenophorin (**1**) (Scheme 1) reveals that they all rest upon the use of reagents with d^1^‐, d^3^‐, or a^2^‐reactivity umpolung for the establishment of at least one of the 1,4‐distances of functional groups. A different approach, outlined in Scheme