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Enantioselectivity of ester aminolysis by optically active surfactants in hexane

โœ Scribed by Kijiro Kon-no; Masaki Tosaka; Ayao Kitahara


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
156 KB
Volume
79
Category
Article
ISSN
0021-9797

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๐Ÿ“œ SIMILAR VOLUMES


Enantioselective cleavage of esters by h
โœ Marco C. Cleij; Wiendelt Drenth; Roeland J. M. Nolte ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 651 KB

## Abstract Cleavage of chiral __p__โ€nitrophenyl esters derived from the amino acid phenylalanine by histidineโ€containing tripeptides has been studied in micellar solutions of four quaternary ammonium surfactants. Enzymeโ€like enantioselectivities up to __k__~__I__~/__k__~__D__~ = 131 (at 0ยฐC) are o