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Enantioselectivity in the Dihydroxylation of Alkenes by Osmium Complexes

✍ Scribed by Gali Drudis-Sole; Gregori Ujaque; Feliu Maseras; Agusti Lledos

Book ID
101991043
Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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πŸ“œ SIMILAR VOLUMES

Dramatic enantioselectivity change in di
Dramatic enantioselectivity change in dihydroxylation of olefins with chiral amine-osmium tetroxide complex
✍ Kiyoshi Tomioka; Makoto Nakajima; Kenji Koga πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 167 KB

## A slight structural modification of a chiral diamine 1 caused a dramatic change in a sense of enantioselectivity in dihydroxylation of olefns with chiral amine-osmium tetroxide complex. Other possible mechanisq involving [3+2] cycloaddition of C=C with O=Os=O in any combinations do not lead to