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Enantioselective total synthesis of natural 11,12-epoxycembrene-C

✍ Scribed by Yulin Li; Zuosheng Liu; Jiong Lan; Jing Li; Lizeng Peng; Weidong Z Li; Ying Li; Albert S.C Chan

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
120 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

The first enantioselective total synthesis of (+)-11,12-epoxycembrene-C (1), a novel naturally occurring cembranoxide isolated from tropical marine soft coral, was achieved via a general approach by employing an intramolecular McMurry coupling and Sharpless asymmetric epoxidation as key steps from readily available starting materials.

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