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Enantioselective Synthesis of α-Methylene-γ-butyrolactones Using Chiral Pd(II)-SPRIX Catalyst.

✍ Scribed by Chinnasamy Muthiah; Midori A. Arai; Toshio Shinohara; Takayoshi Arai; Shinobu Takizawa; Hiroaki Sasai

Publisher: John Wiley and Sons
Year: 2003
Weight: 93 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200341112

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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Enantioselective Hydrogenation of β-Keto Sulfones with Chiral Ru(II)-Catalysts: Synthesis of Enantiomerically Pure Butenolides and γ-Butyrolactones. -A highly enantioselective synthesis of chiral β-hydroxy sulfones (II), (VII) and (XII) is presented involving a novel ruthenium-catalyzed hydrogenati