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Enantioselective synthesis of α-hydroxy thioesters via oxazaborolidine-mediated reduction of α-phenylthio enones

✍ Scribed by Ramon Berenguer; Marta Cavero; Jordi Garcia; Montse Muñoz

Book ID
108386596
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
209 KB
Volume
39
Category
Article
ISSN
0040-4039

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Diastereoselective synthesis of β-amino-
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Reduction of I~-phthalimido-et-keto phosphonates, obtained through an Arbuzov reaction between the appropriate acid chloride and triethyl phosphite, with boranes and oxazaborolidine as catalyst, afforded I~-phthalimido-0t-hydroxy phosphonates in good yields and high diastereoselectivity. Deprotectio

ChemInform Abstract: Diastereoselective
ChemInform Abstract: Diastereoselective Synthesis of β-Amino-α-hydroxy Phosphonates via Oxazaborolidine Catalyzed Reduction of β-Phthalimido-α-keto Phosphonates.
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