Enantioselective Synthesis of Thiosulfinates and of Acyclic Alkylidenemethylene Sulfide Sulfoxides
β Scribed by Stefano Colonna; Vincenza Pironti; Jozef Drabowicz; Franck Brebion; Louis Fensterbank; Max Malacria
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 80 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-193X
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π SIMILAR VOLUMES
## Abstract Enantioselective vanadiumβcatalysed oxidation of aryl benzyl sulfides using Bolmβs procedure is accompanied by kinetic resolution in the oxidation of the resulting sulfoxides which enhances the enantiopurities of the sulfoxides recovered (typically >90β% __ee__), albeit with an associat
## Abstract Enantiomerically pure benzyl sulfoxides are effective tools for the formation of new CβC bonds with control of configuration at new stereogenic centres. The reaction of enantioenriched __tert__βbutyl __tert__βbutanethiosulfinate with benzyllithium derivatives, obtained by deprotonation