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Enantioselective Synthesis of Tertiary Alcohols by the Desymmetrizing Benzoylation of 2-Substituted Glycerols.

✍ Scribed by Byunghyuck Jung; Mi Sook Hong; Sung Ho Kang

Book ID
102000934
Publisher
John Wiley and Sons
Year
2007
Weight
31 KB
Volume
38
Category
Article
ISSN
0931-7597

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Enantioselective Formation of tert-Alkyl
Enantioselective Formation of tert-Alkylamines by Desymmetrization of 2-Substituted Serinols
✍ Mi Sook Hong; Tae Woo Kim; Byunghyuck Jung; Sung Ho Kang 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 253 KB

## Abstract Novel enantioselective desymmetrization of 2‐substituted 2‐amino‐1,3‐propanediols has been established to generate asymmetric quaternary carbon centers comprising an amino group. Enantioselective as well as chemical conversion proved to be greatly dependent on the protecting group of th