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Enantioselective synthesis of natural mesembrine using (D)-mannitol as a chiral template, a model study for the enantioselective synthesis of the amaryllidaceae alkaloids

✍ Scribed by Seiichi Takano; Yoko Imamura; Kunio Ogasawara


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
191 KB
Volume
22
Category
Article
ISSN
0040-4039

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An s-triazine scaffold bearing a free and a protected amino group was synthesised and used for connecting two different and differently derivatised aminoacids. Two diastereoisomeric chiral systems were obtained and, once linked to silica gel, they were used in the chromatographic resolution of struc