𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Enantioselective Synthesis of Herbarumin III by Using a Chelation-Controlled Reduction

✍ Scribed by Gowravaram Sabitha; Chitti Srinivas; Chittapragada Maruthi; Jhillu Singh Yadav

Publisher
John Wiley and Sons
Year
2010
Tongue
German
Weight
163 KB
Volume
93
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The total synthesis of herbarumin III (1) was achieved via an alkynide ion addition onto a chiral aldehyde and LiAlH~4~/LiI reduction as key steps (Scheme 2).

📜 SIMILAR VOLUMES

Synthesis of Lanthanide(III) Chelates by
Synthesis of Lanthanide(III) Chelates by Using ‘Click’ Chemistry
✍ Janne Ketola; Johanna Katajisto; Harri Hakala; Jari Hovinen 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 German ⚖ 113 KB

## Abstract The copper(I)‐catalyzed dipolar [2+3] cycloaddition reaction of an azide and a terminal alkyne is exploited in the preparation of various europium(III), terbium(III), and dysprosium(III) chelates (__Schemes 1–3__). By changing the nature of the alkyne and the azide, a wide range of chel

ChemInform Abstract: Substrate-Controlle
ChemInform Abstract: Substrate-Controlled Formal Synthesis of (+)-Laurenyne by a Chemoselective Chelation-Controlled Alkylation Strategy.
✍ Byungsook Kim; Gukwha Cheon; Janghyun Park; Hyunjoo Lee; Hyoungsu Kim; Sanghee K 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 33 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: Asymmetric Synthesi
ChemInform Abstract: Asymmetric Synthesis of Corsifuran A by an Enantioselective Oxazaborolidine Reduction.
✍ Harry Adams; Nathan J. Gilmore; Simon Jones; Mark P. Muldowney; Stephan H. von R 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 16 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: Stereochemically Co
ChemInform Abstract: Stereochemically Controlled Asymmetric 1,2-Reduction of Enones Mediated by a Chiral Sulfoxide Moiety and a Lanthanum(III) Ion.
✍ Shigeyasu Motohashi; Kouichi Nagase; Toshinori Nakakita; Takeshi Matsuo; Yoshika 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 43 KB

## Abstract Reduction of (Z)‐β‐sulfinyl enones with NaBH~4~/ LaCl~3~·7H~2~O allows efficient access to enantiomerically pure allylic alcohols after desulfuration.