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Enantioselective Synthesis of Garner’s Aldehyde by Asymmetric Hydroformylation

✍ Scribed by Clemens, Alexander J. L.; Burke, Steven D.

Book ID
118021490
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
421 KB
Volume
77
Category
Article
ISSN
0022-3263

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Carbohydrates in asymmetric synthesis: enantioselective allylation of aldehydes
✍ Helmoz R. Appelt; Jane B. Limberger; Minéia Weber; Oscar E.D. Rodrigues; Julieta 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 151 KB

An enantioselective metal-mediated addition of allylic bromides to carbonyl compounds was achieved in the presence of the inexpensive and easily accessible carbohydrates saccharose and b-cyclodextrin. The desired products were obtained in moderate to excellent yields and with up to 93% enantiomeric