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Enantioselective Synthesis of Cordiachromene

✍ Scribed by Samir Bouzbouz; Jean-Yves Goujon; Jerôme Deplanne; Bernard Kirschleger

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 317 KB
Volume: 2000
Category: Article
ISSN: 1434-193X
DOI: 10.1002/1099-0690(200009)2000:18<3223::aid-ejoc3223>3.0.co;2-l

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✦ Synopsis

An enantioselective synthesis of cordiachromene is described. An allylic alcohol moiety is first attached in the oposition to the methoxymethoxy substituent in 1-methoxy-4methoxymethoxybenzene. Then chirality is introduced successively through asymmetric Sharpless epoxidation on the allylic alcohol moiety and regioselective ring-opening. The

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## Abstract For Abstract see ChemInform Abstract in Full Text.