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Enantioselective Synthesis of Binaphthyl Polymers Using Chiral Asymmetric Phenolic Coupling Catalysts: Oxidative Coupling and Tandem Glaser/Oxidative Coupling

✍ Scribed by Morgan, Barbara J.; Xie, Xu; Phuan, Puay-Wah; Kozlowski, Marisa C.

Book ID: 121409988
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 424 KB
Volume: 72
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo070636+

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## Abstract An enantioselective synthesis of the chiral bisnaphthopyrone natural product nigerone and its enantiomer, __ent__‐nigerone, has been realized. The use of constrained 2‐naphthol substrates was critical to producing highly functionalized chiral 1,1′‐binaphthols __via__ asymmetric oxidativ