𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Enantioselective Synthesis of (+)-Anatoxin-a via Enyne Metathesis.

✍ Scribed by Jehrod B. Brenneman; Rainer Machauer; Stephen F. Martin

Publisher
John Wiley and Sons
Year
2004
Weight
29 KB
Volume
35
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Synthesis of constrained Ξ±-amino acid de
Synthesis of constrained Ξ±-amino acid derivatives via enyne metathesis reaction
✍ Sambasivarao Kotha; Nampally Sreenivasachary; Enugurthi Brahmachary πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 221 KB

Synthesis ofa diene building block via enyne metathesis reaction and its usage in the preparation of constrained a-amino acid derivatives is described.

Total synthesis of (Β±)-anatoxin-a via N-
Total synthesis of (Β±)-anatoxin-a via N-acyliminium intermediates
✍ Karen H Melching; Henk Hiemstra; Wim J Klaver; W.Nico Speckamp πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 254 KB

Anatoxin-a has been synthesized in 8 steps, starting from succinimide, 4-bromo-l--butene and dimethyl (2-oxopropyl)phosphonate, by employing as the key step an intramolecular reaction of an N-acyliminium precursor with an cu,&unsaturated ketone moiety, induced by saturated HCl in MeOH at -5OOC. Ana