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Enantioselective Synthesis of a Novel Chiral 2,9-Disubstituted 1,10-Phenanthroline and First Applications in Asymmetric Catalysis

✍ Scribed by Mecheril Valsan Nandakumar; Subrata Ghosh; Christoph Schneider

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 181 KB
Volume: 2009
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200901038

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✦ Synopsis

The asymmetric synthesis of a novel, C 2 -symmetric, tetradentate 1,10-phenanthroline is described; it is based on the stereoselective preparation of two functionalized pyridine subunits, which were subsequently joined through two consecutive carbon-carbon bond-forming reactions to assemble the heteroaromatic system. Some initial applications of this

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