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Enantioselective Synthesis of 3,4-Dihydro-1,2-oxazepin-5(2 H )-ones and 2,3-Dihydropyridin-4(1 H )-ones from β-Substituted β-Hydroxyaminoaldehydes

✍ Scribed by Ranade, Adwait R.; Georg, Gunda I.


Book ID
121455264
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
602 KB
Volume
79
Category
Article
ISSN
0022-3263

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## Abstract The aza‐Wittig reactions of benzaldehyde‐, acetophenone‐ and benzophenone 1‐[(triphenylphosphor‐anylidene)amino]ethylidenehydrazones (**1**) with 2,3‐furandiones **6** provide a new route to 4__H__,8__H__‐1,2,4‐triazolo[1,5‐__c__][1,3]oxazepin‐4‐ones **14** or 5,6‐dihydro‐7__H__,12__H__