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Enantioselective synthesis of (+)-3-isorauniticine via a catalytic tandem palladium-ene/carbonylation reaction

✍ Scribed by Oppolzer, Wolfgang; Bienayme, Hugues; Genevois-Borella, Arielle


Book ID
120332884
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
271 KB
Volume
113
Category
Article
ISSN
0002-7863

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Enantioselective Carbonyl-Ene Reactions
✍ He-Kuan Luo; Lim Bee Khim; Herbert Schumann; Christina Lim; Tan Xiang Jie; Hai-Y πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 245 KB

## Abstract The palladium(II)‐BINAP‐catalyzed enantioselective carbonyl‐ene reactions between ten arylglyoxals and five alkenes were systematically investigated and demonstrated good to excellent enantioselectivities with high __ee__ values of up to 93.8 %. The results showed that both arylglyoxals