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Enantioselective synthesis of 1,1,1-trifluoroalkan-2-ols by ruthenium-catalyzed hydrogenation

✍ Scribed by Yoshichika Kuroki; Daisuke Asada; Yuko Sakamaki; Katsuhiko Iseki

Book ID
108379792
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
216 KB
Volume
41
Category
Article
ISSN
0040-4039

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Ruthenium-Catalyzed Enantioselective Hyd
Ruthenium-Catalyzed Enantioselective Hydrogenation of 1,3-O-Disubstituted 1,3-Dihydroxypropan-2-ones
✍ Edoardo Cesarotti; Patrizia Antognazza; Angela Mauri; Marco Pallavicini; Luigi V πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 German βš– 505 KB

Optically active 1,3-O-disubstituted glycerols were obtained by enantioselective homogeneous hydrogenation of the corresponding 1,3-0 -disubstituted 1,3-dihydroxypropan-2-0nes with different Ru'l-binap complexes. The highest enantioselectivities were obtained with dimeric chloro-ruthenium complexes