Pericyclic cycloaddition reactions are among the most useful transformations available to the synthetic organic chemist. All are capable of simultaneously establishing multiple stereogenic centers with high levels of selectivity. Although many powerful chemical catalysts for these reactions exist, b
✦ LIBER ✦
Enantioselective Ribozyme Catalysis of a Bimolecular Cycloaddition Reaction
✍ Scribed by Burckhard Seelig; Sonja Keiper; Friedrich Stuhlmann; Andres Jäschke
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 107 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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With the exception of work by Goto et al., all these earlier studies considered only a bimolecular reaction with pseudofirst-order kinetics; i.e., first order with respect to the limiting reactant and zero order for the excess reactant. Goto et al. used pseudo-nth-order kinetics. Recently, Beaudry e