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Enantioselective Reactions of N -Acyliminium Ions Using Chiral Organocatalysts

โœ Scribed by Lee, Yong Sup; Alam, Md. Maqusood; Keri, Rangappa S


Book ID
121203757
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
892 KB
Volume
8
Category
Article
ISSN
1861-4728

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Chiral N-acyliminium ions obtained from optically active N- [1-(phenylsulfonyl)alkyl]oxazolidin-2-ones at low temperature in the presence of titanium tetrachloride react with electron-rich aromatic compounds to afford the corresponding adducts in good yields and variable diastereoselectivities. Chem