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Enantioselective Reactions of Donor/Acceptor Carbenoids Derived from α-Aryl-α-Diazoketones

✍ Scribed by Denton, Justin R.; Davies, Huw M. L.


Book ID
121433130
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
201 KB
Volume
11
Category
Article
ISSN
1523-7060

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Dihydrofurans from α-diazoketones: Facil
✍ Elizabeth A. Lund; Isaac A. Kennedy; Alex G. Fallis 📂 Article 📅 1993 🏛 Elsevier Science 🌐 French ⚖ 283 KB

The direct synthesis of diiydmfarans 7.11. and 23-25 from a-diioketones 3.8. and 20-22 is described. l%e cyclopropane iotermedtatcs 9caemted upon treahneait of the a-diazdretoms with metal catalysts in the presence of ethyl vinyl etha nxwnmged sponbmeou3ly. Sensitized llli&wl of 3 afforded 7 pills c