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Enantioselective radical addition reactions to the C?N bond utilizing chiral quaternary ammonium salts of hypophosphorous acid in aqueous media

โœ Scribed by Cho, Dae Hyan; Jang, Doo Ok


Book ID
111647277
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
284 KB
Volume
48
Category
Article
ISSN
1359-7345

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A broad range of fundamental free radical reactions such as hydrogen atom transfer, radical deoxygenations, and radical cyclizations utilizing quaternary ammonium salts of phosphinic acids as chiral and achiral hydrogen donors at room temperature are investigated. The reactions proceed in good to ex