Enantioselective Palladium-Catalyzed Decarboxylative Allylic Alkylations
β Scribed by Shu-Li You; Li-Xin Dai
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 108 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Lithium and magnesium enolates of cyclohexanone undergo palladiumβcatalyzed allylic alkylations under mild conditions. Diastereoselectivity and enantioselectivity are observed when the diphenylβ and dimethylβsubstituted allylic substrates **1a** and **1b** are reacted with cyclohexanone