Enantioselective Organocatalytic Iodination-Initiated Wagner–Meerwein Rearrangement
✍ Scribed by Romanov-Michailidis, Fedor; Guénée, Laure; Alexakis, Alexandre
- Book ID
- 121478723
- Publisher
- American Chemical Society
- Year
- 2013
- Tongue
- English
- Weight
- 623 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1523-7060
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📜 SIMILAR VOLUMES
## Abstract Irradiation of the octalin‐derived sesquiterpene oxide α‐agarofuran in methanol leads to rearrangement to the perhydroazulene system, in addition to simple double‐bond migration to β‐agarofuran. This rearrangement apparently proceeds through a carbonium‐ion‐like intermediate, whereas co
## Abstract The feasibility of the titled reactions for the rapid, enantioselective synthesis of __cis__‐tricyclo[9.3.1.0^3,8^]pentadecane precursors to taxusin and taxol has been examined. The catalysts most well suited to inducing the appropriate 1,2‐shifts have been identified. To a great extent