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Enantioselective organocatalytic conjugate addition of α-nitroacetate to α,β-unsaturated ketones in water

✍ Scribed by Hyoung Wook Moon; Dae Young Kim

Book ID
104097675
Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
359 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis

The catalytic enantioselective conjugate addition reaction of a-nitroacetate to a,b-unsaturated ketones promoted by chiral bifunctional organocatalysts is described. The treatment of a-nitroacetate to a,b-

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Organocatalysis [1] has expanded widely within the last few years, since the rediscovery of the proline-catalyzed aldol reaction. [2] Since then, several different methods, such as fluorination, [3] chlorination, [4] bromination, [5] sulfenylation, [6] amination, [7] and Mannich reactions, [8] have