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Enantioselective Noncovalent Synthesis of Hydrogen-Bonded Double-Rosette Assemblies

✍ Scribed by Leonard J. Prins; Jeroen J. Verhage; Feike de Jong; Peter Timmerman; David N. Reinhoudt


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
347 KB
Volume
8
Category
Article
ISSN
0947-6539

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Diastereoselective Noncovalent Synthesis
✍ Leonard J. Prins; Ron Hulst; Peter Timmerman; David N. Reinhoudt πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 412 KB πŸ‘ 1 views

Chiral centers present either in the dimelamine components of calix[4]arene 1 or in the cyanurate components CA quantitatively induce one handedness (P or M) in the corresponding hydrogen-bonded assemblies 1(3).(CA)(6) (de>98 %). The high degree of chiral induction results from the presence of six c