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Enantioselective michael additions of nitromethane to α,β-unsaturated ketones catalyzed by transition metal complexes with chiral nitrogen ligands

✍ Scribed by A. Schionato; S. Paganelli; C. Botteghi; G. Chelucci


Book ID
103692978
Publisher
Elsevier Science
Year
1989
Weight
531 KB
Volume
50
Category
Article
ISSN
0304-5102

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Enantioselective conjugate addition of f
✍ Hyoung Wook Moon; Min Je Cho; Dae Young Kim 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 245 KB

The catalytic enantioselective conjugate addition reaction of fluorobis(phenylsulfonyl)methane to a,bunsaturated ketones promoted by chiral bifunctional organocatalysts is described. The treatment of fluorobis(phenylsulfonyl)methane to a,b-unsaturated ketones under mild reaction conditions afforded